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UNK32.TXT
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1993-02-13
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4KB
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209 lines
The unknown dissolved in aqueous sodium hydroxide but not sodium bicarbonate.
1348
The compound is a weak acid.
Peak near 4.7 ppm is exchangeable. Solvent is deuterochloroform.
ΦσσσσσΣΣσσσσσσσσσσΣµσσσσσΣσσσσσσσσσσσσσσσσσµµµµµσΣΣΣΣΣΣΣΣσσµµσσσσσσσσσσσσσσσσµσΣΣΣΣΣΣΣΣΣΣΣππΓα▄┘╓╒╘╒╫╪╨╩├╛┬╨╨╘╬╩╠╦─╬╬╓┌▌┌╥╧╚╢╡╣╩┘▄┌┘╓╘╘╒┌█▐αßΓΣΣΣΣΣΣΣΣΣΣπππΣΣππΣΣσσσσσσσσσσσσµµµµµµµµσσσσσσσµµµσσσσσσσσσσσσσσµµσµσσσσσµµµµµµµµµµµµµµµµµµµµµµµµµµµµµµµµµµµµµσµµµ
µµσσσσσµµµσΣπß▄╫╘╬╕┤┐ΓπΣσσσσσσσσσσσσσσσσσσσσσµµµµµµµµµµµµµµµµµµµµµµµττττττττττττµµµµµµµµµµµµτττµµµµµµµµµµµµµµµµµµµµµµµµµµµµσσσµµµµµµµτµτµµµµµµµµµµµµµττµµµµµµτΦττττττττττττµµτττµτΦΦττµττττττττµµσα┘╩èå CÆ▌▀ασΓπΣΣσσσµµµµµµµµµσσσσσσµσσσσµµµµµµµµµµµµµµµµµµµµσσ
µµµµµµµµµµµµµµµµµµµµµµµτττττττµµµµµµµτττµµµµµµµµµµµµµµµµττττττττττττττττΦΦττΦΦτµσσµµτττττΦτΦΦττµπ╓╟┬╩▌ßΣτΦΦτΦΦΦΦΦΦΦΦF¼$z¼!╖ #
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The unknown has 4 aromatic H's, a methyl and an OH group.
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dummy ms
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No extra elements were detected.
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Nitrogen, sulfur and halogens are absent.
The compound burnt with a sooty flame. No residue remained.
#
The compound is aromatic or unsaturated and not a metal salt.
29-31 degrees.
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A low melting solid.
Melt
6788:;<===<:87654554333333568;>AMWbí▓╗┬╠╥╫┘┌┌█▌▌▌▌▌▄▄▄██┌┌╫╓╘╨╬╠╞┐╣╡▒ºí£ûìåÇ}wtojgejwäèÆùÿÖ₧úè|}îÉòÜ¢£ÖÅ}xtt}nYPKHC>=>ADGLIFEBBA????@CDDCBABBA@@BAA@CBBB?<7444688840////-,+*)((&&&'()(*.,))*+)(),.-+**+,,1578:9878<@DEA>;10000.-+,-//0122459<>=851.-----.0379<
<>;40./15:?CJYzî₧í╕╨╥╦£ê`RLHDFHOZxì┤─═╤╘╓╪╧╟└╤╫╘┼└╝úäxolllqv|É₧á¥óº«▓╡╣╜└┬ªé¥îçquàï¬╜╧╙╓╪██╫╘╨╬╘╫╨╞└├╩╧╘├┐⌐ÑÆgnÇæƒ╗┌┌£ÉjZSHEMWnä¥lK73>Qbn[J:3.*)/9KWI0#! !"##$*3=Vü¬┼tMIFA<98;DLYs£└╧▀Φ▐¬}lpïúÿY??@@BDFHIKMNOQSTUUWVZYbd[UVWV[]^sw_TUSSVW[\akç¢ônmyxzu
141922242729423153
The compound is a phenol and shows a 1,2-disubstituted benzene pattern.
190-193 degrees.
#
A moderately high boiling point liquid.
Optically inactive.
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The molecule is not chiral.
Not usually measured for a solid.
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Try this on a liquid.
Not usually measured for a solid.
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Do this on a liquid.
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dummy cmr
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No precipitate was formed.
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The compound is not an aldehyde or ketone.
No reaction at room temperature but a rapid reaction occurred on warming.
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No reaction between solids; on melting the reaction means an OH group.
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No noticeable reaction occurred.
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The unknown is not an ester.
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A reaction. An oily product was formed.
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The unknown has an OH (alcohol or phenol) or NH (prim. or sec. amine) group.
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No noticable reaction.
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The unknown is not easily oxidised.
No positive result.
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The compound can not be easily oxidised.
No colour change was observed.
232850
The unknown is not a carbohydrate.
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A rapid reaction took place giving a gas which fumed in moist air.
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A substitution reaction has occurred (HBr formed); typical of a phenol.
No positive result.
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The unknown is not an ether.
A blue-red colour was formed.
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This unknown is a phenol (or an enol).
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No positive result.
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The compound is not a 1,2-diol.
No apparent reaction.
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The unknown is not a 1,2-diol.
No visible change could be seen.
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The compound is not a primary or secondary alcohol.
## Danger ## very rapid reaction.
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The unknown contains oxygen or nitrogen.
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No reaction was noticed.
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This compound is not a low molecular weight aliphatic alcohol.
Discharge of the reagent's colour was seen.
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The compound could be unsaturated or a phenol.
No reaction took place.
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Absent are groups like esters, acetals, amides and nitriles.
A reaction was observed which gave a liquid product.
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There must be an OH (alcohol or phenol) or NH (prim. or sec. amine) group.
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colourless solid
01050738
0
656669747686
Solid m.p. 54-56 degrees.
White solid m.p. 150-152 degrees.
Crystals m.p. 92-94 degrees.
Solid with m.p. 140-142 degrees.
Crystals m.p. 136-139 degrees.
Melting range 53 to 55 degrees.
3
Ñ¥⌐┬Ñ╗o¼
ê¥│╡┤░y¼┬eë╕½¡
Ñ¥│╡┤░y¼┬eë╕½¡
solid phenol
4
2,4-dimethylphenol
o-cresol
p-cresol
2-methoxyphenol